Mathematical Modeling of Water Management in PEM Fuel Cells

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Liquid water is fundamental to Polymer Electrolyte Membrane fuel cells (PEMFC). Its influence, both beneficial and parasitic, is measured on time scales from femto-seconds to hours, on length scales from Angstroms to centimeters. Its role couples it intimately to all aspects of PEM fuel cell operation: electro-chemical reaction and temperature management, ion transport in the polymer membrane, diffusive mass transport in gas diffusion layers, convective transport in headers and flow fields. A predictive mathematical model for water management must encompass, at some level, these complex interactions over the vast array of length and time scales. This talk will give an over-all sketch of PEMFC functioning, and then will visit in detail the aspects where nano-scales impinge upon the macro-level modeling. In particular we will focus on proton transport modeling in the electrolyte membrane, the multi-phase flow in the teflonated carbon fiber material of the gas diffusion layer which backs the membrane, and the crucial effects which occur at the junction of these two layers.

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Journal: TechConnect Briefs
Volume: 3, Technical Proceedings of the 2003 Nanotechnology Conference and Trade Show, Volume 3
Published: February 23, 2003
Pages: 459 - 462
Industry sectors: Advanced Materials & Manufacturing | Energy & Sustainability
Topic: Fuel cells & Hydrogen
ISBN: 0-9728422-2-5