Nano Science and Technology Institute
Nanotech 2014 Vol. 3
Nanotech 2014 Vol. 3
Nanotechnology 2014: Electronics, Manufacturing, Environment, Energy & Water
Chapter 7: Nanotech & Cleantech for Oil & Gas

Adsorption of Functionalized Silica Nanoparticles on Swelling Clay Minerals

Authors:H.T. Pham, Q.P. Nguyen
Affilation:The University of Texas at Austin, US
Pages:497 - 500
Keywords:nanoparticle, clay, swelling, polyethylene glycol
Abstract:Successful application of nanoparticles is dependent on understanding the mobility, retention, and transport fate of nanoparticles in natural formations. These aspects are greatly influenced by subsurface environmental conditions such as electrolyte type and concentration, temperature, pH and mineral composition of the formation as well as characteristics of the nanoparticle itself such as concentration and surface modifications. Characterizing the effects of surface functionalization and retention of nanoparticles onto clay minerals due to adsorption under subsurface conditions will be necessary for selecting the types of nanoparticles or surface modification to be used as suitable nanosensors or EOR agents. In this study, the effects of surface functionalization through a polyethylene (PEG) coating on 5 nm silica nanoparticle on mobility was evaluated through observations on clay swelling inhibition. Adsorption onto montmorillonite and illite was also investigated. Visual swelling tests were utilized to investigate clay swelling inhibition and ultraviolet-visible (UV-vis) spectroscopy was used to determine the concentration of adsorbed nanoparticles in conditions that are likely to be found in subsurface reservoir environments.
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