Nano Science and Technology Institute
Nanotech 2009 Vol. 2
Nanotech 2009 Vol. 2
Nanotechnology 2009: Life Sciences, Medicine, Diagnostics, Bio Materials and Composites
 
Chapter 8: Polymer Nanotechnology
 

Dynamic rheology and microstructure of polymer/clay nanocomposites prepared under Sc-CO2 by melt compounding

Authors:H.X. Huang, Y. Zhao
Affilation:South China University of Technology, CN
Pages:471 - 473
Keywords:polymer nanocomposite, supercritical carbon dioxide, melt compounding
Abstract:PP- and EVOH-clay nanocomposites were prepared using a twin screw extruder with the aid of supercritical carbon dioxide (Sc-CO2). The dynamic rheological properties were measured using a rheometer in the oscillatory mode. X-ray diffraction and transmission electron microscopy were used to characterize the microstructure of extruded nanocomposites. Results showed that an optimized CO2 concentration existed. When the CO2 concentration increased up to the optimized level, the nanocomposites tended to be more viscous, especially at low frequency, whereas further increasing the CO2 concentration resulted in the decrease in the complex viscosity and dynamic moduli. The presence of Sc-CO2 with a concentration not higher than the optimized level was helpful to promote the degree of dispersion of the nano-clay in polymer matrix, but overloading of CO2 would have a negative effect on the clay dispersion.
Dynamic rheology and microstructure of polymer/clay nanocomposites prepared under Sc-CO2 by melt compoundingView PDF of paper
ISBN:978-1-4398-1783-4
Pages:590
Hardcopy:$179.95
 
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