Nanotech 2008 Vol. 2
Nanotech 2008 Vol. 2
Nanotechnology 2008: Life Sciences, Medicine & Bio Materials - Technical Proceedings of the 2008 NSTI Nanotechnology Conference and Trade Show, Volume 2

Environment, Health & Toxicology Chapter 2

Nanofiltration of Electrolyte Solutions by Sub-2nm Carbon Nanotube Membranes

Authors: F. Fornasiero, H.G. Park, J.K. Holt, M. Stadermann, S. Kim, J.B. In, C.P. Grigoropoulos, A. Noy, O. Bakajin

Affilation: Lawrence Livermore National Laboratory, United States

Pages: 106 - 109

Keywords: carbon nanotube membrane, desalination, ion selectivity, Donnan theory

Abstract:
Both MD simulations and experimental studies have shown that liquid and gas flow through carbon nanotubes with nanometer size diameter is exceptionally fast. For applications in separation technology, selectivity is required together with fast flow. In particular, for water desalination, coupling the enhancement of the water flux with selective ion transport could drastically reduce the cost of brackish and seawater desalting. In this work, we use pressure-driven filtration experiments to study ion exclusion in silicon nitride/CNT composite membranes as a function of solution ionic strength, pH, and ion valence. The pores of these membranes are sub-2-nm diameter CNTs whose entrance is decorated by negatively charged carboxylic groups. We show that carbon nanotube membranes exhibit significant ion exclusion at low salt concentration. Our results support a Donnan-type rejection mechanism, dominated by electrostatic interactions between fixed membrane charges and mobile ions, while steric and hydrodynamic effects appear to be less important. Comparison with commercial nanofiltration membranes for water softening reveals that our carbon nanotube membranes provides far superior water fluxes for similar ion rejection capabilities.


ISBN: 978-1-4200-8504-4
Pages: 808
Hardcopy: $159.95

2015 & Newer Proceedings

Nanotech Conference Proceedings are now published in the TechConnect Briefs

NSTI Online Community