Nano Science and Technology Institute
Nanotech 2006 Vol. 3
Nanotech 2006 Vol. 3
Technical Proceedings of the 2006 NSTI Nanotechnology Conference and Trade Show, Volume 3
Chapter 1: Nano and Molecular Electronics and Photonics

Kinetics in two Phase-Observe Interaction and Identify the Binding Parameters

Authors:V. Yadav and A. Pandey
Affilation:University Grant Commission, IN
Pages:98 - 102
Keywords:kinetics, oxidation, alcohol, SLS and vanadium(V)
Abstract:Kinetic and mechanistic studies of some alcohols viz., allyl, crotyl, methyl and ethyl alcohol using quinquevalent vanadium in aqueous and anionic micellar media are discussed. Oxidation follows first order kinetics with respect to [V(V)], [Substrate] and [H+]. The presence of anionic surfactant viz., Sodium lauryl sulphate enhances the reaction rate. Broxton method is utilized for the determination of CMC and thermodynamic parameters viz. DE#, DH#, DG#, DS# have been computated. The mechanism is consistent with the observed results has been discussed.
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